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← All Experiments Structure 2.2 — Molecular Shapes

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Bond angle

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Central atom (dark)
Bonding pair
Lone pair
Bond angle arc

3D Molecular Geometry

Interactive

Valence Shell Electron Pair Repulsion

Electron pairs (bonding and lone) around a central atom repel each other and arrange themselves to maximize the distance between them.

Key rule: Lone pairs repel more strongly than bonding pairs. This means lone pairs compress bond angles below the ideal values.

The order of repulsion: LP-LP > LP-BP > BP-BP. Each lone pair reduces the bond angle by approximately 2.5°.

IB Exam Strategy

"Predict and explain" questions require: (1) State the electron domain geometry, (2) Count lone pairs, (3) State the molecular shape, (4) Give the bond angle.

Common mistake: Confusing electron domain geometry with molecular shape. CH₄ and NH₃ both have tetrahedral electron domains, but NH₃ is trigonal pyramidal because the lone pair is not "seen".

Data Booklet: You must know the shapes and angles — they are NOT given in the exam.

SL Shape Reference